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Empirical Formula for combustion:

The Ideal Gas Law is used to determine the molar mass and from that the molecular formula

$PV = nRT$ $n = \frac{PV}{RT}$

P = kPa V = L R = 8.314 T = K ($\degree C + 273.15$)

Given mass of substance, and by figuring out moles, you can find its molar mass.